Citation
Zainab Ngaini, . and Cammidge Andrew N., . (2008) Novel surface-functionalised nanoparticles as polymer supports for synthesis of unsymmetrical porphyrins. [Proceedings Paper]
Abstract
A polymerisable surfactant containing a reactive polymerisable tail and polar carboxylic acid head group was synthesized and employed in the development of surface functionalised nanoparticles via microemulsion polymerisation. The average diameter of the polymer was 317 nm with a size range of 56-600 nm. The feasibility of using this polymer as a solid support in organic chemistry has been successfully demonstrated in the synthesis of unsymmetrical porphyrins where higher yields were achieved compared to the same reactions in solution or on conventional solid-phase.
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Abstract
A polymerisable surfactant containing a reactive polymerisable tail and polar carboxylic acid head group was synthesized and employed in the development of surface functionalised nanoparticles via microemulsion polymerisation. The average diameter of the polymer was 317 nm with a size range of 56-600 nm. The feasibility of using this polymer as a solid support in organic chemistry has been successfully demonstrated in the synthesis of unsymmetrical porphyrins where higher yields were achieved compared to the same reactions in solution or on conventional solid-phase.
Additional Metadata
| Item Type: | Proceedings Paper |
|---|---|
| Additional Information: | Available at Perpustakaan Sultan Abdul Samad Uni-versiti Putra Malaysia 43400 UPM Serdang Selangor Malaysia. mal RM666 H33 B573 Call Number |
| AGROVOC Term: | Polymers |
| AGROVOC Term: | Porphyrins |
| AGROVOC Term: | Chemical structure |
| AGROVOC Term: | Filtration |
| AGROVOC Term: | Purification |
| AGROVOC Term: | Precipitation |
| AGROVOC Term: | Solvents |
| AGROVOC Term: | Potassium |
| AGROVOC Term: | Ethanol |
| AGROVOC Term: | Melting point |
| Geographical Term: | MALAYSIA |
| Depositing User: | Ms. Suzila Mohamad Kasim |
| Last Modified: | 24 Apr 2025 05:15 |
| URI: | http://webagris.upm.edu.my/id/eprint/12871 |
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