Effect of immersion time in water on the tensile properties of acetylated steam-exploded acacia mangium fibers filled polyethylene composites


Citation

R.M. Taib, . and S. Ramarad, . and Z.A. Mohd Ishak, . and H.D. Rozman, . (2006) Effect of immersion time in water on the tensile properties of acetylated steam-exploded acacia mangium fibers filled polyethylene composites. [Proceedings Paper]

Abstract

Steam-exploded fibers were derived from steam explosion of Acacia mangium wood chips. The fibres after undergoing water and alkali extractions AEF were acetylated with acetic anhydride. Weight percent gain WPG of the acetylated fibers AAEF were 4.9 13.7 and 18.3. Composites of high-density polyethylene HDPE and acetylated steam-exploded Acacia mangium fibers were prepared using 2 roll mill and compression molding. The composites tensile specimenswere immersed in water at room temperature for 30 days. All composites absorbed water but the water uptake was found to decreased with increasing WPG of AAEF fibers. Acetylation had decreased the number of accessible hydroxyl groups of AAEF fibers to interact with water molecules. The tensile properties of the immersed samples were tested after 2 4 and 6 days of water immersion. The tensile properties of HDPE-AEF and HDPE-AAEF composites were observed to decreased with immersion time. HDPE-AEF composites showed a reduction in maximum stress and tensile modulus after 2 days of water immersions. HDPE-AAEF composites on the other hand showed a distinct decreased in both properties after 4 days of water immersion. All composites exhibited higher percent decreased in tensile modulus than maximum stress. The decrease in tensile modulus in particular was lower for composites filled with AAEF fibers of higher WPG. Tensile modulus too was found to decrease linearly R20.80 with increasing water uptake to the composite system. Acetylation did not improve fiber-matrix interaction but did reduce the amount of water absorbed by the composite system.


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Abstract

Steam-exploded fibers were derived from steam explosion of Acacia mangium wood chips. The fibres after undergoing water and alkali extractions AEF were acetylated with acetic anhydride. Weight percent gain WPG of the acetylated fibers AAEF were 4.9 13.7 and 18.3. Composites of high-density polyethylene HDPE and acetylated steam-exploded Acacia mangium fibers were prepared using 2 roll mill and compression molding. The composites tensile specimenswere immersed in water at room temperature for 30 days. All composites absorbed water but the water uptake was found to decreased with increasing WPG of AAEF fibers. Acetylation had decreased the number of accessible hydroxyl groups of AAEF fibers to interact with water molecules. The tensile properties of the immersed samples were tested after 2 4 and 6 days of water immersion. The tensile properties of HDPE-AEF and HDPE-AAEF composites were observed to decreased with immersion time. HDPE-AEF composites showed a reduction in maximum stress and tensile modulus after 2 days of water immersions. HDPE-AAEF composites on the other hand showed a distinct decreased in both properties after 4 days of water immersion. All composites exhibited higher percent decreased in tensile modulus than maximum stress. The decrease in tensile modulus in particular was lower for composites filled with AAEF fibers of higher WPG. Tensile modulus too was found to decrease linearly R20.80 with increasing water uptake to the composite system. Acetylation did not improve fiber-matrix interaction but did reduce the amount of water absorbed by the composite system.

Additional Metadata

[error in script]
Item Type: Proceedings Paper
Additional Information: 6 ills 1 table. 5 refs.
AGROVOC Term: WATER VAPOUR
AGROVOC Term: FIBRES
AGROVOC Term: ACETYLATION
AGROVOC Term: POLYETHYLENE
AGROVOC Term: ABSORPTION
AGROVOC Term: WATER
AGROVOC Term: MALAYSIA
Geographical Term: MALAYSIA
Depositing User: Ms. Norfaezah Khomsan
Last Modified: 24 Apr 2025 05:28
URI: http://webagris.upm.edu.my/id/eprint/17019

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