Singlet oxygeneration cis and trans-1 4-polyisoprene and cis-2 6-dimethylocta-2 6-diene

Arnold A.R., . and Boon A.J., . and Courtneidge J.L., . and Farley P.S., . Singlet oxygeneration cis and trans-1 4-polyisoprene and cis-2 6-dimethylocta-2 6-diene. pp. 261-274. ISSN 0127-7065

Mono- and bis-hydroperoxides have been isolated from the reaction between singlet oxygen and 2 6-dimethyl-2 6-octadiene and their Hydrogen-1 NMR spectral parameters are given. This information is used to examine both new and previously published Hydrogen-1 and Carbob-13 NMR data for the products of the reactions between singlet oxygen and both natural rubber and Gutta Percha. The relevance of these results to chain mobility in polyisoprenes is discussed

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Abstract

Mono- and bis-hydroperoxides have been isolated from the reaction between singlet oxygen and 2 6-dimethyl-2 6-octadiene and their Hydrogen-1 NMR spectral parameters are given. This information is used to examine both new and previously published Hydrogen-1 and Carbob-13 NMR data for the products of the reactions between singlet oxygen and both natural rubber and Gutta Percha. The relevance of these results to chain mobility in polyisoprenes is discussed

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Item Type:	Article
Additional Information:	4 ill.; 6 tables; 19 ref.; Summary (En)
AGROVOC Term:	HEVEA BRASILIENSIS
AGROVOC Term:	GUTAPERCHA
AGROVOC Term:	QUIMICA
AGROVOC Term:	ESTRUCTURA QUIMICA
Depositing User:	Ms. Norfaezah Khomsan
Last Modified:	24 Apr 2025 05:56
URI:	http://webagris.upm.edu.my/id/eprint/20501

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