Citation
Kamaliah Sirat, . and Smith Peter W., . Dimethylsulphoxide complexes of vanadium (III). pp. 137-143. ISSN 0126-6128
Abstract
Dimethylsulphoxide (DMSO) complex salts of vanadium(III) with the empirical formulae VCI3.6DMS0 and VBr3.6DMS0 were synthesized and investigated. The observed infra-red band positions of the v(SO) stretch indicate that the ligand is coordinated to vanadium ion via oxygen. Far-infra-red spectra lead to the conclusion that none of the halide ions are coordinated to the metal ion. Diffuse reflectance spectra are consistent with vanadium in an octahedral environment. Accordingly the chloride and bromide salts are formulated as V(DMSO)6CI3 and VDMSO6Br3 respectively.
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Abstract
Dimethylsulphoxide (DMSO) complex salts of vanadium(III) with the empirical formulae VCI3.6DMS0 and VBr3.6DMS0 were synthesized and investigated. The observed infra-red band positions of the v(SO) stretch indicate that the ligand is coordinated to vanadium ion via oxygen. Far-infra-red spectra lead to the conclusion that none of the halide ions are coordinated to the metal ion. Diffuse reflectance spectra are consistent with vanadium in an octahedral environment. Accordingly the chloride and bromide salts are formulated as V(DMSO)6CI3 and VDMSO6Br3 respectively.
Additional Metadata
| Item Type: | Article |
|---|---|
| AGROVOC Term: | Vanadium |
| AGROVOC Term: | Nitrogen |
| AGROVOC Term: | Hydration |
| AGROVOC Term: | Salts |
| AGROVOC Term: | Spectral analysis |
| AGROVOC Term: | Ligands |
| AGROVOC Term: | Chlorides |
| AGROVOC Term: | Bromides |
| Geographical Term: | Malaysia |
| Depositing User: | Ms. Suzila Mohamad Kasim |
| Last Modified: | 28 Apr 2025 00:10 |
| URI: | http://webagris.upm.edu.my/id/eprint/22796 |
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