Citation
Arnold A. R., . and Boon A. J., . and Courtneidge J. L., . and Farley P. S., . Singlet oxygenation of cis and trans-1 4-polyisoprene and cis-2 6-dimethylocta-2 6-diene. pp. 261-274. ISSN 0127-7065
Abstract
Mono- and bis-hydroperoxides have been isolated from the reaction between singlet oxygen and 2 6-dimethyl-2 6-octadiene and their H NMR spectral parameters are given. This information is used to examine both new and previously published H and 13C NMR data for the products of the reactions between singlet oxygen and both natural rubber and Gutta Percha. The relevance of these results to chain mobility in polyisoprenes is discussed.
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Abstract
Mono- and bis-hydroperoxides have been isolated from the reaction between singlet oxygen and 2 6-dimethyl-2 6-octadiene and their H NMR spectral parameters are given. This information is used to examine both new and previously published H and 13C NMR data for the products of the reactions between singlet oxygen and both natural rubber and Gutta Percha. The relevance of these results to chain mobility in polyisoprenes is discussed.
Additional Metadata
| Item Type: | Article |
|---|---|
| AGROVOC Term: | Rubber |
| AGROVOC Term: | Natural rubber |
| AGROVOC Term: | Gutta-percha |
| AGROVOC Term: | Oxygen |
| AGROVOC Term: | Chemical reactions |
| AGROVOC Term: | Polymers |
| AGROVOC Term: | Spectroscopy |
| AGROVOC Term: | Chromatography |
| AGROVOC Term: | High performance liquid chromatography |
| AGROVOC Term: | Polymerization |
| Depositing User: | Ms. Suzila Mohamad Kasim |
| Last Modified: | 24 Apr 2025 06:28 |
| URI: | http://webagris.upm.edu.my/id/eprint/23463 |
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