Citation
Gelling I. R., . and Tinker A. J., . and Haidzir Abdul Rahman, . Solubility parameters of epoxidised natural rubber. pp. 20-29. ISSN 0127-7065
Abstract
Solubility parameter values have been obtained for a series of epoxidised natural rubbers (ENR) both by calculation and from equilibrium swelling data. A 41 mole epoxidised synthetic cis-1 4-polyisoprene was also included in the study; its solubility parameter was determined by the viscosity technique. Solubility parameters increased in a linear manner with the extent of epoxidation. These data can be employed to predict a number of ENR properties e.g. polymer solubility solvent resistance and compatibility with other polymers. However any specific solvent/ENR or polymer/ENR interactions such as dipole or hydrogen-bonding forces can lead to erroneous conclusions unless these are also taken into account.
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Abstract
Solubility parameter values have been obtained for a series of epoxidised natural rubbers (ENR) both by calculation and from equilibrium swelling data. A 41 mole epoxidised synthetic cis-1 4-polyisoprene was also included in the study; its solubility parameter was determined by the viscosity technique. Solubility parameters increased in a linear manner with the extent of epoxidation. These data can be employed to predict a number of ENR properties e.g. polymer solubility solvent resistance and compatibility with other polymers. However any specific solvent/ENR or polymer/ENR interactions such as dipole or hydrogen-bonding forces can lead to erroneous conclusions unless these are also taken into account.
Additional Metadata
| Item Type: | Article |
|---|---|
| AGROVOC Term: | Natural rubber |
| AGROVOC Term: | Hevea rubber |
| AGROVOC Term: | Epoxides |
| AGROVOC Term: | Latex |
| AGROVOC Term: | Viscosity |
| AGROVOC Term: | Polymers |
| AGROVOC Term: | Vulcanization |
| AGROVOC Term: | Resistance to chemicals |
| AGROVOC Term: | Physical properties |
| AGROVOC Term: | Self compatibility |
| Depositing User: | Ms. Suzila Mohamad Kasim |
| Last Modified: | 24 Apr 2025 06:28 |
| URI: | http://webagris.upm.edu.my/id/eprint/23469 |
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