Relationships between structure and performance of vulcanisates


Citation

Campbell D. S., . and Chapman A. V., . Relationships between structure and performance of vulcanisates. pp. 246-258. ISSN 0127-7065

Abstract

Available experimental procedures for estimating chemical crosslink density in rubber vulcanisates and the present state of knowledge of the correlation of chemical crosslink structure with properties of natural rubber vulcanisates are critically assessed. Differentiation is made between correlations with technological test data and with chemical constitution. The difficulties associated with quantitative measurement of chemical crosslink density in gum and filled systems are reviewed and the discussion is amplified by specific reference to published work on the rote of polysulphide crosslinks in determining strength properties.


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Abstract

Available experimental procedures for estimating chemical crosslink density in rubber vulcanisates and the present state of knowledge of the correlation of chemical crosslink structure with properties of natural rubber vulcanisates are critically assessed. Differentiation is made between correlations with technological test data and with chemical constitution. The difficulties associated with quantitative measurement of chemical crosslink density in gum and filled systems are reviewed and the discussion is amplified by specific reference to published work on the rote of polysulphide crosslinks in determining strength properties.

Additional Metadata

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Item Type: Article
AGROVOC Term: Natural rubber
AGROVOC Term: Hevea rubber
AGROVOC Term: Vulcanization
AGROVOC Term: Cross-linking
AGROVOC Term: Polymers
AGROVOC Term: Hardness
AGROVOC Term: Chemical structure
AGROVOC Term: Chemicophysical properties
AGROVOC Term: Tensile strength
AGROVOC Term: Strength
Depositing User: Ms. Suzila Mohamad Kasim
Last Modified: 24 Apr 2025 06:28
URI: http://webagris.upm.edu.my/id/eprint/23511

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