Curing kinetics thermal and mechanical properties of epoxy layered silicate nanocomposite toughened with modified natural rubber

M. Khairulazfar, . and N. Y. Yuhana, . and S. Dzuhri, . Curing kinetics thermal and mechanical properties of epoxy layered silicate nanocomposite toughened with modified natural rubber. pp. 1-18. ISSN 1511-1768

The glass transition temperature Tg curing kinetics mechanical properties and morphology of the diglycidyl ether of bisphenol A (DGEBA) toughened with liquid epoxidised natural rubber (LENR) and Cloisite 30B as filler were studied. Poly(etheramine) was used as the curing agent at different ratios. Mechanical stirring was used for the mixing process and the samples were cured at room temperature. Generally it was found that epoxy toughened with modified natural rubber showed higher values of Tg compared to the unmodified epoxy system. Compared to other epoxy-LENR samples five grams of LENR per 100g of epoxy resin produced a higher result for the tensile Youngs modulus. The addition of clay nanoparticles (Cloisite 30B) with a high amine ratio increased the Tg and mechanical properties of the system. The activation energy Ea of the curing reaction was obtained using the Kissinger and Flynn-Wall-Ozawa method. The ternary system containing 2g of Cloisite 30B in 5g of LENR per 100g of epoxy resin (R5C2 system) showed the lowest Ea value. This system reached maximum curing in the shortest time. It was observed that a higher amount of rubber content in the material gave larger size rubber particles and hence led to lower mechanical properties. SEM images of fractured samples showed that adhesion of rubber with epoxy seemed to be poor when using higher rubber content while the use of lower amine ratio material might result in unreacted areas that imparted poor mechanical properties.

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Abstract

The glass transition temperature Tg curing kinetics mechanical properties and morphology of the diglycidyl ether of bisphenol A (DGEBA) toughened with liquid epoxidised natural rubber (LENR) and Cloisite 30B as filler were studied. Poly(etheramine) was used as the curing agent at different ratios. Mechanical stirring was used for the mixing process and the samples were cured at room temperature. Generally it was found that epoxy toughened with modified natural rubber showed higher values of Tg compared to the unmodified epoxy system. Compared to other epoxy-LENR samples five grams of LENR per 100g of epoxy resin produced a higher result for the tensile Youngs modulus. The addition of clay nanoparticles (Cloisite 30B) with a high amine ratio increased the Tg and mechanical properties of the system. The activation energy Ea of the curing reaction was obtained using the Kissinger and Flynn-Wall-Ozawa method. The ternary system containing 2g of Cloisite 30B in 5g of LENR per 100g of epoxy resin (R5C2 system) showed the lowest Ea value. This system reached maximum curing in the shortest time. It was observed that a higher amount of rubber content in the material gave larger size rubber particles and hence led to lower mechanical properties. SEM images of fractured samples showed that adhesion of rubber with epoxy seemed to be poor when using higher rubber content while the use of lower amine ratio material might result in unreacted areas that imparted poor mechanical properties.

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Item Type:	Article
AGROVOC Term:	Natural rubber
AGROVOC Term:	Epoxides
AGROVOC Term:	Mixing
AGROVOC Term:	Heating
AGROVOC Term:	Curing (processing)
AGROVOC Term:	Stirring
AGROVOC Term:	Near infrared spectroscopy
AGROVOC Term:	Electron microscopy
AGROVOC Term:	Catalysts
AGROVOC Term:	Molecular weight
Depositing User:	Ms. Suzila Mohamad Kasim
Last Modified:	24 Apr 2025 06:28
URI:	http://webagris.upm.edu.my/id/eprint/23644

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