Citation
Scott G., . Some new concepts in the stabilisation of polymers. pp. 163-177. ISSN 0127-7065
Abstract
Recent research has shown that a variety of antioxidants have the ability to trap alkyl radicals under conditions of rapid radical generation and/or low oxygen pressure chain-breaking acceptor (CB-A) process. When the antioxidant has a well characterised oxidised and reduced form the resulting redox couple may give rise to a catalytic antioxidant effect under certain conditions. Such a CB-A/CB-D catalytic effect has been known to operate in polypropylene during processing and in rubber during fatiguing. It is also believed to account for the high fatigue resistance of sulphur vulcanisates.
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Abstract
Recent research has shown that a variety of antioxidants have the ability to trap alkyl radicals under conditions of rapid radical generation and/or low oxygen pressure chain-breaking acceptor (CB-A) process. When the antioxidant has a well characterised oxidised and reduced form the resulting redox couple may give rise to a catalytic antioxidant effect under certain conditions. Such a CB-A/CB-D catalytic effect has been known to operate in polypropylene during processing and in rubber during fatiguing. It is also believed to account for the high fatigue resistance of sulphur vulcanisates.
Additional Metadata
Item Type: | Article |
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AGROVOC Term: | Hevea rubber |
AGROVOC Term: | Rubber |
AGROVOC Term: | Polymers |
AGROVOC Term: | Antioxidants |
AGROVOC Term: | Catalytic activity |
AGROVOC Term: | Vulcanization |
AGROVOC Term: | Oxidation |
AGROVOC Term: | Sulphur |
AGROVOC Term: | Stabilization |
AGROVOC Term: | Chemical structure |
Depositing User: | Ms. Suzila Mohamad Kasim |
Last Modified: | 24 Apr 2025 06:28 |
URI: | http://webagris.upm.edu.my/id/eprint/23503 |
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